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The deprotonated dyes have the HOMO localized both on the Hcyanine scaffold and the bridgehead amine, whereas the LUMO is distributed only along the polymethine chain, indicating a potent charge transfer from the terminal amine to Hcyanine

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A standard refrigerator (around 2-8C or 36-46F) is an acceptable, though less ideal, alternative for shorter-term storage, perhaps a few months