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This S is called a thiolate and its really unhappy and thus reactive An oxidizing state in your cells can thus be dangerous because inappropriate bridging can occur if they get oxidized by reactive oxygen species (ROS)

LaccID as a genetically encoded tag for EM Genetically encoded labels analogous to GFP for fluorescence microscopy are highly valuable for marking organelles, proteins and other cellular features in EM

Nagata J, Kobayashi M, Nishikimi N, Komori K

From a clinical perspective, these findings underscore the potential of the GSTT1 null genotype as a genetic marker for HNC susceptibility, which could have significant implications for early detection and prevention strategies

Nitric oxide destroys zinc-sulfur clusters inducing zinc release from metallothionein and inhibition of the zinc finger-type yeast transcription activator LAC9