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doi: 10.2337/db08-0604 101 XuLSpinasGANiessenM

[18] [19] From uroporphyrinogen III to precorrin-2 [edit] The enzyme CobA catalyses two methylations, to give precorrin-2: [20] (1a) uroporphyrinogen III + S-adenosyl methionine precorrin-1 + S-adenosyl-L-homocysteine (1b) precorrin-1 + S-adenosyl methionine precorrin-2 + S-adenosyl-L-homocysteine From precorrin-2 to precorrin-3A [edit] The enzyme CobI then converts this to precorrin-3A: [18] precorrin-2 + S-adenosyl methionine precorrin-3A + S-adenosyl-L-homocysteine From precorrin-3A to precorrin-3B [edit] Next, the enzyme CobG transforms precorrin-3A to precorrin-3B: [18] precorrin-3A + NADH + H + + O 2 precorrin-3B + NAD + + H 2 O This enzyme is an oxidoreductase that requires oxygen and hence the reaction can only operate under aerobic conditions

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This signaling pathway is critically involved in the regulation of cell growth, (anti-)apoptosis, translation, but also the basic carbon metabolism (Courtnay et al., 2015) (Figure 2)