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Available from: says that these withdrawal symptoms can be observed in a person within 24-48 hours after he/she last smoked

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The formation of pyrazines begins during the tobacco curing process, where amino acids and reducing sugars undergo Maillard reactions

It has also been proposed that the vehicle in which the allergen reaches the skin could take some responsibility in the sensitization of the epidermis by both assisting the percutaneous penetration and causing some form of trauma and mobilization of cytokines itself